Homologous series

In chemistry, homologous series is a series of organic compounds with similar chemical properties, members of which differ by a constant relative molecular mass.

Alkanes (paraffins), alkenes (olefins), and alkynes (acetylenes) form such series in which members differ in mass by 14, 12, and 10 atomic mass units, respectively. For example, the alkane homologous series begins with methane (CH4), ethane (C2H6), propane (C3H8), butane (C4H10), and pentane (C5H12), each member differing from the previous one by a CH2 group (or 14 atomic mass units).

Compounds in each set have the same little group of atoms called the functional group. Most chemical properties of organic compounds are due to the presence of the functional group.

Homologous SeriesGeneral FormulaExampleFunctional Group
Alkanes CnH2n+2 (n more than or equal to 1) CH4, n=1
Alkenes CnH2n (n more than or equal to 2) C2H4, n=2 C = C
Alcohols CnH2n+2O (n more than or equal to 1) CH4O, n=1 - OH
Carboxylic Acids CnH2nO2 (n more than or equal to 1) CH2O2, n=1 - COOH

Where n represents the number of carbon atoms.

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See also: Homologous series, Alcohols, Alkane, Alkanes, Alkene, Alkenes, Alkyne, Atomic mass, Butane